Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 85, Pages 15502-15505Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc06276d
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Funding
- French Agence Nationale de la Recherche [ANR-12-BSV8-0001]
- Japan Society for the Promotion of Science [25870400]
- Agence Nationale de la Recherche (ANR) [ANR-12-BSV8-0001] Funding Source: Agence Nationale de la Recherche (ANR)
- Grants-in-Aid for Scientific Research [25870400] Funding Source: KAKEN
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A 4th electron transferring tryptophan in animal cryptochromes and (6-4) photolyases is discovered and functionally analyzed by transient absorption. It yields a much longer-lived flavin-tryptophan radical pair than the mere tryptophan triad in related flavoproteins, questioning the putative role of the primary light reaction of cryptochrome in animal magnetoreception.
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