Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 65, Pages 12974-12976Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc04323a
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Funding
- DST, India, under FAST Track Scheme [SR/FT/CS-118/2010]
- MINECO of Spain (FEDER funds) [CONSOLIDER INGENIO 2010 CSD2010-00065, CTQ2014-57393-C2-1-P]
- Department of Science and Technology, Govt. of West Bengal [280(Sanc.)/ST/P/ST/4G-10/2009]
- Single Crystal Diffractometer Facility at the Department of Chemistry, Jadavpur University
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A novel thiocyanate bridged 2D MOF, [CdL(mu-1,3-SCN)(2)](n), [HL = 2-(2-(ethylamino)ethyliminomethyl)-6-ethoxyphenol] has been synthesized and characterized by X-ray crystallography. The band gap of the synthesized material in the solid state has been determined by experimental measurements and compared with the theoretical value obtained from DFT calculations. For the first time, the single crystal X-ray crystallography of a MOF has been reported along with its applicability in photosensitive devices.
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