Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 59, Pages 11802-11805Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc02995c
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Funding
- European Research Council through AdG ROCOCO
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Linking together an oligourea and an oligoamide foldamer gives rise to a conformationally well-defined structure, despite the different hydrogen-bonding patterns in the two domains, provided the oligomers are ligated amide C terminus to urea N terminus. A powerful screw-sense preference induced at the N terminus of the resulting chimeric structure provides evidence for cooperative conformational interactions within the 'block co-foldamer'.
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