Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 58, Pages 11642-11645Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc04219d
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Funding
- NSF [DMR-0922588, CHE 0087210, DMR 1337296]
- Ohio Board of Regents [CAP-491]
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [1337296] Funding Source: National Science Foundation
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1,3,5-Tris(4-carboxyphenyl) benzene assembles into an intricate 8-fold polycatenated assembly of (6,3) hexagonal nets formed through hydrogen bonds and pi-stacking. One polymorph features 56 independent molecules in the asymmetric unit, the largest Z' reported to date. The framework is permanently porous, with a BET surface area of 1095 m(2) g(-1) and readily adsorbs N-2, H-2 and CO2.
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