4.7 Article

Bifunctional covalent organic frameworks with two dimensional organocatalytic micropores

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 2, Pages 310-313

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc07104b

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Funding

  1. CSIR-Nehru science postdoctoral research fellowship
  2. CSIR [CSC0122, CSC0102]

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We report the successful incorporation of bifunctional (acid/base) catalytic sites in the crystalline organocatalytic porous COF (2,3-DhaTph). Due to the presence of acidic (catachol) and basic (porphyrin) sites, 2,3-DhaTph shows significant selectivity, reusability, and excellent ability to perform the cascade reaction.

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