Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 100, Pages 17688-17691Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc07025b
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Funding
- 973 projects [2012CB619401, 2012CB619402]
- NSFC [21473129, 21201137, 21103137, 21503155, IRT13034]
- China Postdoctoral Science Foundation [2014M552425]
- National Young 1000-Plan'' program
- Wuhan National High Magnetic Field Centre
- Fundamental Research Funds for Central Universities
- US National Science Foundation [CHE-1152609]
- NSF [DMR-1157490]
- State of Florida
- US Department of Energy
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1152609] Funding Source: National Science Foundation
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Two mononuclear square-planar Cr(II) complexes are reported, exhibiting field-induced slow magnetic relaxation. The axial zero-field splitting parameter was unambiguously determined by both a high-frequency/field electron paramagnetic resonance (HF-EPR) technique and magnetic measurements. This result represents the first observed single-molecule-magnet behavior in the square planar coordination geometry of any metal ions.
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