Thiophene-fused bowl-shaped polycyclic aromatics with a dibenzo[a,g] corannulene core for organic field-effect transistors

For the first time, electron-rich thiophene units were fused into the skeleton of corannulene to extend pi-surfaces and tune arrangement in single crystals. Two isomeric butterfly-like thiophene-fused dibenzo[a, g]corannulenes (3 and 5) were synthesized. Isomer 3 showed p-type transport properties, with a hole mobility of 0.06 cm(2) V-1 s(-1).