Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 56, Pages 11276-11279Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc02989a
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Funding
- European Union [FP7-270028]
- Polish Ministry of Science and Higher Education [0322/IP3/2013/72]
- German Research Foundation (DFG) [SFB 951]
- European Regional Development Fund [POIG.02.01.00-12-023/08]
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Based on scanning tunneling microscopy experiments, we show that the covalent coupling of aryl halide monomers on the rutile TiO2(011)-(2 x 1) surface is controlled by the density of surface hydroxyl groups. The efficiency of the polymerization reaction depends on the level of surface hydroxylation, but the presence of hydroxyl groups is also essential for the reaction to occur.
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