Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 32, Pages 6884-6900Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc10194d
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Funding
- NSFC [21202027]
- NCET [NCET-12-0145]
- Technology foundation for Selected Overseas Chinese Scholar'' of the Ministry of Human Resources and Social Security of China
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Over the past decade, the effectiveness of i-PrMgCl center dot LiCl has been constantly highlighted by a number of research groups. Its enhanced nucleophilicity brings prosperity to highly functionalized Grignard reagents, other useful bimetallic (alkali-metal) agents and nucleophilic alkylation products under mild reaction conditions. In this feature article, a comprehensive, systematical and in-depth overview of i-PrMgCl center dot LiCl is provided in a multidisciplinary idea. It involves the structural and kinetic perspectives of i-PrMgCl center dot LiCl as well as its unique reactivity and selectivity, with knowledge of the former helping to rationalize trends of the later.
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