4.7 Article

A water-stable lanthanide-organic framework as a recyclable luminescent probe for detecting pollutant phosphorus anions

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 51, Pages 10280-10283

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc02596f

Keywords

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Funding

  1. 973 Program [2012CB821702, 2011CB935902]
  2. NSFC [21421001, 21473121]
  3. 111 project [B12015]
  4. MOE Innovation Team of China [IRT13022, IRT-13R30]

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A novel 3D Eu-BTB framework (1) containing three types of 1D channels was synthesized and structurally characterized. Compound 1 exhibits high thermostability and water stability with the pH range from 2 to 12. Additionally, the luminescence explorations revealed that 1 can sensitively and selectively detect pollutant PO43-among various colourless anions. More importantly, 1 represents the first example of regenerable MOF-based luminescent probes for detecting PO43-.

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