Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 33, Pages 7257-7260Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc01331c
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Funding
- Scientific Research Fund of Sichuan Provincial Education Department [13ZB0173, 13TD0022]
- Open Project of State Key Laboratory Cultivation Base for Nonmetal Composites and Functional Materials [11zxfk26, 13zxfk06]
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Palladium catalyzed selective mono-arylation of o-carboranes with aryl iodides has been developed, and a series of B(8)/B(9)-Ar-o-carboranes anchored with active groups have been synthesized with moderate to good yield as well as good selectivity. The mechanism involving Pd-II catalyzed electrophilic B-H activation was also proposed.
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