Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 30, Pages 6508-6511Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc01378j
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Funding
- MEXT, Japan
- MEXT
- Grants-in-Aid for Scientific Research [15H02177, 14J00792] Funding Source: KAKEN
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The first nickel-catalyzed method for the borylation of carbon-hydrogen bonds in arenes and indoles is described. The use of an N-heterocyclic carbene ligand is essential for an efficient reaction, with an N-cyclohexyl-substituted derivative being optimal. This method is readily applied to the gram scale synthesis of 2-borylindole.
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