Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 57, Pages 11374-11377Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc02179k
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Funding
- National Natural Science Foundation of China [21172151, 21432006, 21321061]
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A highly efficient catalytic kinetic resolution of 2,3-epoxy 3-aryl ketones via asymmetric ring-opening with pyrazole derivatives has been achieved by using a chiral N,N'-dioxide-Sc(III) complex as the catalyst. A wide variety of substrates were readily scoped, and the selectivity factors obtained were excellent (up to > 300).
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