Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 21, Pages 4406-4409Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc00410a
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- University of Oxford
- Agency of Science, Technology and Research (A*STAR) Singapore
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Pd-II-catalysed ortho-arylation of benzylic heterocycles with arylboronic acid pinacol esters (Ar-BPin) via directed C-H bond activation to generate the desired biaryl products is reported. This methodology is efficient and applicable to a wide range of functionalised Ar-BPin and benzylic heterocycles, allowing the direct synthesis of important biaryl motifs in modest to good yield.
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