Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 155, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.inoche.2023.111073
Keywords
Fluorine; Titanium oxide; Organic dye; Thin films; Photocatalysis
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Bare titanium oxide (TiO2) and fluorine (F) doped TiO2 thin films were successfully fabricated on soda lime glass substrates using the sol-gel dip-coating technique. The influence of hydrofluoric acid (HF) concentration on the structural, optical, and photocatalytic properties of the films was investigated. Characterization techniques such as X-ray diffraction, scanning electron microscopy, X-ray photo-electron spectroscopy, energy dispersive X-ray spectroscopy, atomic force microscopy, and UV-visible spectrophotometry were employed. The results showed the presence of highly crystalline anatase phase TiO2, cracked surfaces in the SEM images, and a decrease in roughness with increasing HF concentration in the AFM images.
In this work, we have successfully fabricated bare titanium oxide (TiO2) and fluorine (F) doped TiO2 thin films via the sol-gel dip-coating technique on the soda lime glass substrates. The effect of hydrofluoric acid (HF) concentration on the structural, optical, and photocatalytic properties of TiO2 thin films is investigated. The films are characterized by the X-ray diffraction (XRD) technique, scanning electron microscopy (SEM), X-ray photo-electron spectroscopy (XPS), energy dispersive X-ray spectroscopy (EDS), atomic force microscopy, and UV-visible spectrophotometer. The XRD patterns show the presence of highly crystalline anatase phase TiO2. The SEM images reveal some cracked surfaces, while the EDX reveals the absence of fluorine in all samples. The AFM images exhibit a decrease in roughness with the increase in HF concentration. UV-visible spectrometry reveals high transparency in the visible region (about 85%) and the shift in absorption edge toward the higher energy side. To evaluate the photocatalytic performance of the photocatalysts, methylene blue (MB) dye is chosen as a model pollutant. The photocatalytic test shows a decrease in the degradation rate of MB with the increase in HF concentration in the solution. This work will trigger the development of highly efficient acid-modified photo-catalysts for environmental remediation.
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