☆ 4.7 Article

Cooperative Spin-State Switching and Vapochromism of Mononuclear Ni(II) Complexes by Pyridine Coordination/Decoordination

INORGANIC CHEMISTRY (2023)

Related references

Note: Only part of the references are listed.

Article Chemistry, Multidisciplinary

Vapor-triggered reversible crystal transformation of a nickel-based magnetic molecular switch

Shufang Xue et al.

Summary: This study demonstrates the vapor-triggered crystal-to-crystal transformation between a discrete trinuclear complex and a two-dimensional coordination polymer. The transformation exhibits a coordination-induced spin state switch behavior attributed to the structural phase transition triggered by solvent signal, which can be detected reversibly through optical and magnetic responses.

CHEMICAL COMMUNICATIONS (2022)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Reversible coordination-induced spin state switching in a nickel(ii) complex via a crystal-to-crystal transformation

Yaqian Zhao et al.

Summary: The recent upsurge in coordination-induced spin state switching (CISSS) is being applied in the areas of switchable contrast agents for magnetic resonance imaging (MRI) and molecular spintronics. In this study, a novel CISSS behavior driven by solvent desorption-triggered single-crystal-to-single-crystal (SCSC) deligation process is found in a dinuclear nickel(ii) complex. The thermal stability, crystal structures, thermochromism, and magnetic properties provide evidence for this behavior. Additionally, the reversible crystal transformation accompanied by optical and magnetic responses in cycles suggests a new strategy for developing external-stimuli CISSS materials.

INORGANIC CHEMISTRY FRONTIERS (2022)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Elastic Crystalline Fibers Composed of a Nickel(II) Complex

Sotaro Kusumoto et al.

Summary: This study demonstrates the generation of elastic crystalline fibers from nonfibrous crystals of metal complexes by applying mechanical stimuli to platelike crystals of Ni-II(salophen). The high elasticity of the resulting crystal fibers is attributed to the presence of molecular strands composed of slip-stacked arrangement by nearly planar Ni(salophen) molecules. However, the flexibility of these fibers is lost upon the introduction of chloroform solvent molecules into the crystal lattice during recrystallization.

INORGANIC CHEMISTRY (2021)

Add to Collection

Article Chemistry, Multidisciplinary

A Fluorescence-Detected Coordination-Induced Spin State Switch

Hannah Kurz et al.

Summary: The study presents a family of planar nickel(II) complexes with sensitive CISSS tracked by fluorescence detection. These complexes fluoresce in noncoordinating solvents but are fluorescence-silent in the presence of axial ligands. FD-CISSS shows higher sensitivity compared to absorption-based CISSS.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Vapochromism and Magnetochemical Switching of a Nickel(II) Paddlewheel Complex by Reversible NH3 Uptake and Release

Katharina M. Fuerpass et al.

Summary: The reaction of [NiCl2(PnH)(4)] with NiCl2 yields a binuclear paddlewheel complex capable of reversibly binding and releasing NH3, showing distinctive vapochromic properties and magnetochemical switching. Detailed SQUID measurements reveal that in the complex, only the Ni atom coordinated to the NH3 molecule is responsible for its paramagnetic behavior.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Vapochromic behaviour of a nickel(ii)-quinonoid complex with dimensional changes between 1D and higher

Ryota Yano et al.

Summary: The nickel(ii)-chloranilato complex displays reversible vapochromism even after the removal of coordinated vapour molecules, maintaining its spin state and six-coordinate geometry. The unique vapochromism, influenced by the weaker ligand field of the chloranilate ligand, is related to dimensional changes between 1D and higher dimensions.

DALTON TRANSACTIONS (2021)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Solvent Effect on the Spin State of an Iron(II)-Triazole Trimer

Irene Sanchez-Molina et al.

Summary: The study presents a triazole-based trinuclear iron(II) compound with solvatochromic spin crossover behavior, where magnetic properties depend on the crystallization solvent molecules. Immersion of crystals in different solvents can promote color change, providing insights into the solvent-induced switching process. This research contributes important details to understanding the solvatochromism in spin crossover materials, offering potential alternatives for controlling switching and their application as colorimetric sensors.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Ferromagnetically Coupled Hydroxo-bridged Heptanuclear Ni(II) Wheel Cluster with S=7 Ground Spin State

Sotaro Kusumoto et al.

CHEMISTRY LETTERS (2020)

Add to Collection

Article Chemistry, Multidisciplinary

CO2-Induced Spin-State Switching at Room Temperature in a Monomeric Cobalt(II) Complex with the Porous Nature

Manabu Nakaya et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Add to Collection

Review Chemistry, Multidisciplinary

Functional metal-organic frameworks as effective sensors of gases and volatile compounds

Hai-Yang Li et al.

CHEMICAL SOCIETY REVIEWS (2020)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Covalent post-synthetic modification of switchable iron-based coordination polymers by volatile organic compounds: a versatile strategy for selective sensor development

Esther Resines-Urien et al.

DALTON TRANSACTIONS (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Interplay between spin-crossover and luminescence in a multifunctional single crystal iron(ii) complex: towards a new generation of molecular sensors

Bouabdellah Benaicha et al.

CHEMICAL SCIENCE (2019)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Design, synthesis, and evaluation of nickel dipyridylmethane complexes for Coordination-Induced Spin State Switching (CISSS)

Michaela Klass et al.

DALTON TRANSACTIONS (2018)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Creating capsules with cubanes

Sotaro Kusumoto et al.

DALTON TRANSACTIONS (2018)

Add to Collection

Review Chemistry, Multidisciplinary

Guest-Dependent Spin-Transition Behavior of Porous Coordination Polymers

Ryo Ohtani et al.

CHEMISTRY-A EUROPEAN JOURNAL (2017)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Dehydration of Octacyanido-Bridged NiII-WIV Framework toward Negative Thermal Expansion and Magneto-Colorimetric Switching

Mateusz Reczynski et al.

INORGANIC CHEMISTRY (2017)

Add to Collection

Article Chemistry, Multidisciplinary

CrystalExplorer model energies and energy frame-works: extension to metal coordination compounds, organic salts, solvates and open-shell systems

Campbell F. Mackenzie et al.

IUCRJ (2017)

Add to Collection

Article Chemistry, Multidisciplinary

Methanol-Triggered Vapochromism Coupled with Solid-State Spin Switching in a Nickel(II)-Quinonoid Complex

Paramita Kar et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

Add to Collection

Article Chemistry, Multidisciplinary

Proton-driven coordination-induced spin state switch (PD-CISSS) of iron(II) complexes

Rene Nowak et al.

CHEMICAL COMMUNICATIONS (2017)

Add to Collection

Article Chemistry, Multidisciplinary

Reversible quantitative guest sensing via spin crossover of an iron(II) triazole

Reece G. Miller et al.

CHEMICAL SCIENCE (2016)

Add to Collection

Article Chemistry, Multidisciplinary

Coordination-Induced Spin-State-Switch (CISSS) in water

Marcel Dommaschk et al.

CHEMICAL COMMUNICATIONS (2014)

Add to Collection

Article Materials Science, Multidisciplinary

Particle tuning and modulation of the magnetic/colour synergy in Fe(II) spin crossover-polymer nanocomposites in a thermochromic sensor array

Alejandro Lapresta-Fernandez et al.

JOURNAL OF MATERIALS CHEMISTRY C (2014)

Add to Collection

Article Chemistry, Multidisciplinary

Photographing the synergy between magnetic and colour properties in spin crossover material [Fe(NH2trz)3](BF4)2: a temperature sensor perspective

Alejandro Lapresta-Fernandez et al.

CHEMICAL COMMUNICATIONS (2013)

Add to Collection

Article Chemistry, Multidisciplinary

Vapochromic Ionic Liquids from Metal-Chelate Complexes Exhibiting Reversible Changes in Color, Thermal, and Magnetic Properties

Yusuke Funasako et al.

CHEMISTRY-A EUROPEAN JOURNAL (2012)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Spin-crossover in cobalt(II) compounds containing terpyridine and its derivatives

Shinya Hayami et al.

COORDINATION CHEMISTRY REVIEWS (2011)

Add to Collection

Article Chemistry, Multidisciplinary

Light-Induced Spin Change by Photodissociable External Ligands: A New Principle for Magnetic Switching of Molecules

Steffen Thies et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)

Add to Collection

Article Multidisciplinary Sciences

Magnetic Bistability of Molecules in Homogeneous Solution at Room Temperature

S. Venkataramani et al.

SCIENCE (2011)

Add to Collection

Article Chemistry, Multidisciplinary

Reversible Magnetism between an Antiferromagnet and a Ferromagnet Related to Solvation/Desolvation in a Robust Layered [Ru2]2TCNQ Charge-Transfer System

Natsuko Motokawa et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)

Add to Collection

Article Chemistry, Multidisciplinary

Bidirectional Chemo-Switching of Spin State in a Microporous Framework

Masaaki Ohba et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2009)

Add to Collection

Review Chemistry, Multidisciplinary

Magnetic metal-organic frameworks

Mohamedally Kurmoo

CHEMICAL SOCIETY REVIEWS (2009)

Add to Collection

Article Chemistry, Multidisciplinary

Synthesis and alcohol vapor sensitivity of a ferromagnetic copper-tungsten bimetallic assembly

Shin-ichi Ohkoshi et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2007)

Add to Collection

Article Chemistry, Inorganic & Nuclear

1-D cobalt(II) spin transition compound with strong interchain interaction:: [Co(pyterpy)Cl2]•X

S Hayami et al.

INORGANIC CHEMISTRY (2004)

Add to Collection

© Peeref 2019-2024. All rights reserved.