Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 38, Pages 8134-8137Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc01587a
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Funding
- NSFC [21002043, 21272107]
- National S&T Major Project of China [2012ZX09504-001-003]
- Fundamental Research Funds for the Central Universities [lzujbky-2013-166]
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A highly diastereoselective annulation of simple aldehydes and 5-alkenyl thiazolones, via oxidative NHC catalysis has been developed. This strategy provides facile access to a diverse library of functionalized chiral thiazolo pyrones. Aerobic oxygen can also be applied as a secondary oxidant to avoid the use of stoichiometric organic or inorganic oxidants.
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