Journal
INDUSTRIAL CROPS AND PRODUCTS
Volume 204, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.indcrop.2023.117319
Keywords
Biodiesel; Jatropha oil; Reusability; Kinetic study
Categories
Ask authors/readers for more resources
This paper introduces a novel and efficient magnetic nanocatalyst, Mg@CoFe2O4, for producing biodiesel from Jatropha oil. Various analyzes were employed to characterize the nanocomposite, and the optimal variables for biodiesel generation were determined using response surface methodology. The nanocatalyst showed remarkable catalytic performance and reusability. Thermodynamics and kinetics analysis indicated that the reaction is endothermic and the reaction speed is enhanced with increasing temperature. Overall, the Mg@CoFe2O4 nanocatalyst is highly recommended for further investigation due to its excellent performance in biodiesel production.
This paper aims to develop a novel and efficient magnetic nanocatalyst for producing biodiesel from Jatropha oil. Therefore, Mg@CoFe2O4 nanocomposite as a retrievable, and strong catalyst was synthesized and employed for transesterification of Jatropha oil. After that, various analyzes were employed for characterizing Mg@CoFe2O4 nanocomposite, including XRD, Raman, FTIR, FESEM, EDX, CO2/TPD, BET, VSM, and TEM. These analyzes confirmed that Mg was successfully decorated on CoFe2O4. Response surface methodology (RSM) was employed to optimize efficient variables on biodiesel generation. The utmost biodiesel efficiency utilizing CoFe2O4 and Mg@CoFe2O4 nanocatalysts were 93.99 % and 95.49 %, respectively, which are obtained at ultrasonication time of 32.21 and 33.96 min, respectively. These biodiesel yields indicate the extraordinary efficiency of both nanocatalysts. Also, Mg@CoFe2O4 indicated a high biodiesel yield (i.e., 87.43 %) after seven reuse steps, indicating the remarkable reusability of this nanocatalyst. The thermodynamics and kinetics of transesterification showed that the biodiesel generation reaction is endothermic and the reaction speed enhanced with enhancing temperature. Moreover, decoration of CoFe2O4 with Mg led to improved catalytic performance and boosted biodiesel yield. Overall, the Mg@CoFe2O4 nanocatalyst is strongly recommended for future investigation owing to its excellent biodiesel performance, short reaction time, and extraordinary reusability of the catalyst.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available