Journal
INDUSTRIAL CROPS AND PRODUCTS
Volume 203, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.indcrop.2023.117193
Keywords
Deep eutectic solvents (DES); Sugarcane pith; Lignin-containing cellulose nanofibril (LCNF); LCNF paper; Diols
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In this study, a green and one-pot strategy was developed to fractionate sugarcane pith cellulose and lignin. The obtained lignin-containing cellulose nanofibrils (LCNFs) had well-defined structure and uniform size distribution, while the fractionated lignin showed reduced heterogeneity and condensation under acidic conditions. Furthermore, multi-functional LCNF papers with excellent properties were successfully prepared. This study demonstrated the hierarchical biomass utilization and production of high-value building blocks using a tailored deep eutectic solvent and ultrasonic pretreatments.
The recalcitrant nature of plant cells makes biomass hierarchical utilization challenging. Here we report a green, one-pot strategy to achieve fractionation of sugarcane pith cellulose and lignin. Lignin-containing cellulose nanofibrils (LCNFs) and fractionated lignin (by tailored choline chloride and oxalic acid-based deep eutectic solvents (DESs) and ultrasonic nanofibrillation pretreatments) were studied. The obtained LCNFs had a well independent structure and uniform size distribution (5.05-6.88 nm in diameter). Lignin fractionated by diol acid DES (DADES) exhibited a relatively homogeneous molecular weight (Mw, 2013-2827 g/mol), reduced lignin heterogeneity, and condensation under acidic conditions. Besides, multi-functional LCNF papers were prepared by vacuum filtration of their suspensions and had excellent bio-disintegration capability, water resistance, UV-shielding performance, and thermal stability. This study demonstrated that DADES enables hierarchical biomass utilization and successful production of high-value-added building blocks, such as LCNF and fractionated lignin.
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