Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 10, Pages 1870-1873Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc09303h
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Funding
- Danish National Research Foundation [DNRF59]
- Villum Foundation
- Danish Council for Independent Research: Technology and Production Sciences
- Lundbeck Foundation
- Carlsberg Foundation
- Aarhus University
- Chinese Scholarship Council
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The carbonylative coupling of aryl and heteroaryl bromides with polyfluoroarenes via palladium-catalyzed C-H activation is presented. This transformation proceeds efficiently at moderate reaction temperatures and does not require strong base or reactive intermediates. A near stoichiometric amount of CO is sufficient and the methodology can thus be easily expanded to include the preparation of [C-13]-acyl labeled benzopolyfluorophenones.
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