4.7 Article

Photocatalytic CO2 reduction using visible light by metal-monocatecholato species in a metal-organic framework

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 92, Pages 16549-16552

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc04506a

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Funding

  1. Department of Energy, Office of Basic Energy Sciences, Division of Materials Science and Engineering [DE-FG02-08ER46519]
  2. Korea Center for Artificial Photosynthesis [2009-0093881]

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Metal-organic frameworks (MOFs) with isolated metal-monocatecholato groups have been synthesized via postsynthetic exchange (PSE) for CO2 reduction photocatalyst under visible light irradiation in the presence of 1-benzyl-1,4-dihydronicotinamide and triethanolamine. The Cr-monocatecholato species are more efficient than the Ga-monocatecholato species.

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