4.7 Article

Red, far-red, and near infrared photoswitches based on azonium ions

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 65, Pages 12981-12984

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc02804c

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Funding

  1. Natural Sciences and Engineering Research Council of Canada

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Azonium ions formed by p-amino substituted azo compounds with both ortho- and meta-methoxy substituents exhibit strong absorbance in far-red and near infrared spectral region. The compounds undergo robust photoswitching in aqueous solution and exhibit a range of thermal relaxation rates from 10 mu s-100 ms.

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