4.7 Article

Copper-catalyzed silylation of p-quinone methides: new entry to dibenzylic silanes

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 100, Pages 17684-17687

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc06653k

Keywords

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Funding

  1. European Research Council [ERC-337776]
  2. MINECO [CTQ2012-35957]
  3. MICINN

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An efficient and general copper(I)-catalyzed silylation of p-quinone-methides is described. Non-symmetric dibenzylic silanes are obtained in high yields under mild reaction conditions. These compounds can be used as bench-stable benzylic carbanion precursors.

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