4.7 Article

Polypyrrole hollow nanospheres: stable cathode materials for sodium-ion batteries

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 89, Pages 16092-16095

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc04229a

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Funding

  1. Commonwealth of Australia through the Automotive Australia Cooperative Research Centre (AutoCRC)
  2. Fundamental Research Funds for the Central Universities of China [NE2014301]
  3. Australian Research Council (ARC) Linkage, Infrastructure, Equipment and Facilities (LIEF) grant [LE0237478]

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Hollow polypyrrole (PPy) nanospheres with high sodium storage capacity as cathode materials for Na-ion batteries were reported. PPy hollow nanospheres demonstrated high current rate capacity and good cyclability. It was revealed by electrochemical testing and DFT calculation that the as-prepared PPy hollow nanospheres participate in reversible doping/de-doping reactions.

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