Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 26, Pages 5725-5727Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc01084e
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Funding
- National Science Foundation of China [21472162]
- Thousand Youth Talents Plan
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The highly enantioselective cobalt-catalyzed hydroboration reaction of aryl ketones with HBpin was developed using iminopyridine oxazoline ligands. Halides, amines, ethers, sulfides, esters and amides are well tolerated under the mild reaction conditions, demonstrating its synthetic advantage. Substituted diaryl ketones could also be hydroborated with high enantioselectivity.
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