Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 82, Pages 15129-15132Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc04013b
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Funding
- University Grant commission (UGC), New Delhi
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Direct, regioselective and metal-free synthesis of fused N-heterocyclic iodides is reported. This regioselective C-H functionalization is mediated by tert-butylhydroperoxide (TBHP), via dual activation of molecular iodine and a heterocyclic substrate, resulting in the in situ generation of electrophilic iodine species (I+), and free radical(s) (BuO center dot)-Bu-t or (BuOO center dot)-Bu-t, driving the iodination reaction.
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