Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 37, Pages 7871-7874Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc00758e
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Funding
- National Natural Science Foundation of China [21302200]
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A Rh(III)- or Ir(III)-catalyzed direct aldehyde C-H alkynylation was developed for the first time as a simple and practical method for the synthesis of ynones. This catalytic reaction proceeds under mild reaction conditions and tolerates a variety of synthetically important functional groups (e.g., chloro, bromo, aldehyde), thus providing a good complement to previous methods.
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