4.7 Article

Electrochemical driven water oxidation by molecular catalysts in situ polymerized on the surface of graphite carbon electrode

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 37, Pages 7883-7886

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc00242g

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Funding

  1. Swedish Research Council
  2. K & A Wallenberg Foundation
  3. Swedish Energy Agency
  4. China Scholarship Council (CSC)
  5. National Natural Science Foundation of China [21120102036]
  6. National Basic Research Program of China [2014CB239402]

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A simple strategy to immobilize highly efficient ruthenium based molecular water-oxidation catalysts on the basal-plane pyrolytic graphite electrode (BPG) by polymerization has been demonstrated. The electrode 1@BPG has obtained a high initial turnover frequency (TOF) of 10.47 s(-1) at similar to 700 mV overpotential, and a high turnover number (TON) up to 31600 in 1 h electrolysis.

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