Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 8, Pages 1417-1420Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc09242b
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Funding
- Center of Biomolecular Structure and Dynamics CoBRE [NIGMS P20GM103546]
- National Science Foundation (NSF)-MRI [CHE-1337908]
- University of Montana (UM)
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1337908] Funding Source: National Science Foundation
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H-1 NMR spectroscopic and X-ray crystallographic investigations of a 1,3-bis(4-ethynyl-3-iodopyridinium) benzene scaffold with perrhenate reveal strong halogen bonding in solution, and bidentate association in the solid state. A nearly isostructural host molecule demonstrates significant C-H hydrogen bonding to perrhenate in the same phases.
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