Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 48, Pages 9884-9887Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc02741a
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Funding
- NSF of China [21322606, 21436005]
- Doctoral Fund of Ministry of Education of China [20120172110012]
- Fundamental Research Funds for the Central Universities
- Guangdong NSF [S2011020002397, 2013B090500027, 10351064101000000]
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We present a general strategy for incorporating pi-conjugated NNN-chelators (e.g., terpyridyl moiety) into a porous metal-organic framework (MOF) MIL-101(Cr) by using the click post-functionalization. The functionalized MOF could be used as a platform for metalation to yield highly active and stable single-site heterogeneous metal (e.g., Ru(III)) catalysts.
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