Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 93, Pages 16613-16616Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc07463k
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Funding
- Platform for Drug Discovery, Informatics, and Structural Life Science from MEXT, Japan
- AMED, Japan
- JSPS KAKENHI Grant [15H03118, 26560443, 26350971]
- Grants-in-Aid for Scientific Research [15H01554] Funding Source: KAKEN
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An efficient deborylthiolation of aryl- and alkenylborons with thio-sulfonates has been achieved under mild conditions using a copper catalyst. All steps of the experimental process were free from unpleasant odors. The mild reaction conditions as well as ready availability of boron compounds and thiosulfonates enabled easy access to an array of sulfides, including those bearing sensitive functional groups.
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