Journal
FUEL PROCESSING TECHNOLOGY
Volume 249, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.fuproc.2023.107843
Keywords
Lignin; Guaiacol; Lewis acid; C-ar-C-alpha bond; Catalysis
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This study reports a strategy for directly cleaving the C-ar-C-alpha and C-beta-O bonds in pine lignin over a solid acid to produce guaiacol. The guaiacol yield in a 90% methanol aqueous solution is 18.2 wt%, which is 5.6 wt% higher than that in methanol. The reaction pathway is proposed based on controlled experiments and density functional theory, showing the relationship between deacetylation, C-alpha=O bond formation, and C-ar-C-alpha bond cleavage.
Guaiacol is an important raw material to produce many value-added chemicals. Here, we report a strategy for directly cleaving the C-ar-C-alpha and C-beta-O bonds in pine lignin over a solid acid to generate guaiacol. The guaiacol yield in 90% methanol aqueous solution is up to 18.2 wt%, which is 5.6 wt% higher than that in methanol. The reaction pathway is proposed by combining controlled experiments with density functional theory. Different from previous views, the C-ar-C-alpha bond cleavage was found to be related to deacetylation, while the formation of C-alpha=O bond was found to change the intramolecular charge distribution and promote the C-ar-C-alpha bond cleavage through validation experiments. Adding water promotes methanol decomposition to produce more active hydrogen species and thereby promote the C-ar-C-alpha bond cleavage. This work provided a feasible pathway for obtaining guaiacol by directly cleaving the C-ar-C-alpha and C-beta-O bonds in lignin.
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