4.7 Article

Facet-dependent acidic and catalytic properties of sulfated titania solid superacids

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 75, Pages 14219-14222

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc04548g

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Funding

  1. National Natural Science Foundation [21371035, 21173050]
  2. SINOPEC [X514005]

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Sulfated titania solid superacids with dominant {001}, {001}/{101}, and {101} facets were prepared by the hydrothermal method and subsequent sulfation. Their facet-dependent acidic properties were investigated by the solid-state P-31 NMR technique and Pechmann condensation of 5,7-dihydroxy-4-methyl coumarin.

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