4.7 Article

A hierarchically core/shell-structured titanosilicate with multiple mesopore systems for highly efficient epoxidation of alkenes

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 80, Pages 14905-14908

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc05278e

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Funding

  1. NSFC of China [21533002, 21373089]
  2. Programs Foundation of Ministry of Education [2012007613000]

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A hierarchical titanosilicate, with epitaxially grown MFI nanosheets on microsized TS-1 crystals, has been prepared through a desilication-recrystallization method using a diammonium surfactant as the secondary structure-directing agent (SDA). This core/shell material features multiple mesoporosities, significantly improved epoxidation activity as well as easy separation in synthesis and catalytic reactions.

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