Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 47, Pages 9655-9658Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc02760h
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Funding
- NEXT (Japan) program (Strategic Molecular and Materials Chemistry through Innovative Coupling Reactions) of Hokkaido University
- JSPS KAKENHI [15H03804, 15K13633]
- JSPS
- Grants-in-Aid for Scientific Research [15K13633, 14J02447, 14J02341] Funding Source: KAKEN
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The selective boryl substitution of alkyl halides bearing terminal C=C double bonds has been achieved using a copper(I)/tricyclohexylphosphine or copper(I)/o-diphenylphosphinophenol catalyst. This reaction represents a useful complementary approach to conventional procedures for the hydroboration of C=C double bonds or the borylative cyclization of alkyl halides bearing terminal alkenes.
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