4.2 Article

Synthesis and polymerization of disiloxane Si-O-Si-linked phthalonitrile monomer

Journal

MENDELEEV COMMUNICATIONS
Volume 26, Issue 6, Pages 527-529

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.mencom.2016.11.023

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Funding

  1. Russian Federation Ministry of Education and Science [02.G25.31.0114]

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A novel low melting highly hydrolytically stable phthalonitrile monomer containing Ar-Si-O-Si-Ar bonds with T-g = 4 degrees C exhibits good rheological properties. Its cured resin possesses high heat deflection temperature (T-hd = 471 degrees C) and demonstrates high thermal and thermooxidative stabilities (T-5% = 503 degrees C, TOS5% = 495 degrees C, = 76%) that are typical of phthalonitrile matrices.

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