4.7 Article

Efficient electrochemiluminescence of a readily accessible boron difluoride formazanate dye

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 18, Pages 3766-3769

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc10038g

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Funding

  1. Natural Sciences and Engineering Research Council of Canada (NSERC)
  2. Canada Foundation for Innovation (CFI)
  3. University of Western Ontario

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Electrochemiluminescence (ECL) of a boron difluoride formazanate dye was investigated in the presence of tri-n-propylamine as a reductive co-reactant. The ECL mechanism was studied using ECL-voltage curves, spooling ECL, and accumulative ECL spectroscopy. The ECL occurs at 724 nm by three distinct, voltage-dependent mechanisms of light emission.

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