4.7 Article

A Br-substituted phenanthroimidazole derivative with aggregation induced emission from intermolecular halogen-hydrogen interactions

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 29, Pages 6350-6353

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc00490j

Keywords

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Funding

  1. National Basic Research Program of China [2013CB834803]
  2. National Natural Science Foundation of China [91222202, 21171114]
  3. Scientific Research Start-up Funds of Shanxi University [020354010]

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A unique aggregation induced emission (AIE) active emitter based on a Br-substituted phenanthroimidazole derivative was reported. The yellowish green emission with high quantum yield and a large Stokes shift (similar to 150 nm) in the aggregated state is proposed to be obtained from weak interactions especially C-H center dot center dot center dot Br interactions.

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