Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 28, Pages 6175-6178Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc01530h
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Funding
- National Natural Science Foundation of China [21172026]
- Scientific Research Fund of Liaoning Provincial Education Department [L2012024]
- Chang Jiang Scholars Program from Ministry of Education of the People's Republic of China [T2011056]
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The oxazolidine-2,4-dione motif is found frequently in biologically important compounds. A tandem phosphorus-mediated carboxylative condensation of primary amines and alpha-ketoesters/base-catalyzed cyclization reaction have been developed. These processes provide a novel and convenient access to various oxazolidine-2,4-diones in a one-pot fashion using atmospheric carbon dioxide and readily available substrates under very mild and transition-metal-free conditions.
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