4.7 Article

Sharp molecular-sieving of alcohol-water mixtures over phenyldiboronic acid pillared graphene oxide framework (GOF) hybrid membrane

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 34, Pages 7345-7348

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc00924c

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Funding

  1. National 863 Project [2012AA050104]
  2. Advanced Coal Project [XDA07040400]
  3. SARI [Y426473231]
  4. NSFC [21403281]

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A submicron thick diboronic acid linked GOF/polyvinyl alcohol hybrid membrane was prepared for the first time. The uniform inter-spacing of the GOF membrane excludes the diffusion of large molecules based on a molecular sieving mechanism. It exhibits high stability and excellent sieving performance in solvent (>= C3) dehydration (SFs > 10 000).

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