4.7 Article

Cheap carbon black-based high-performance electrocatalysts for oxygen reduction reaction

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 10, Pages 1972-1975

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc07677j

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Funding

  1. National Basic Research Program of China (973 Program) [2012CB932800, 2014CB932700]
  2. National Natural Science Foundation of China [21273220, 21073180]
  3. the Recruitment Program of Global youth Experts of China

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A family of cheap carbon black based Fe-N-x/C electrocatalysts with superhigh-performance for oxygen reduction reaction (ORR) were synthesized. The one with Fe 10 wt% and N 1.57 wt% shows the best performance. The activity order of different active sites for ORR was revealed firstly: Fe-N-4/2-C > Fe-4-N-C > N-C >> Fe-4-C approximate to C.

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