Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 4, Pages 689-692Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc07719a
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Funding
- National 973 Basic Research Program [2012CB933800]
- National Natural Science Foundation of China [21035002, 21275070, 21305060, 21327902]
- National Science Fund for Creative Research Groups [21121091]
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We propose a strategy to control directly the orientation of hemin plane via experimental models, Hemin-His model and Hemin-MHN model with ODT. Electrochemical results show that electron communication is largely enhanced when the hemin plane is near to parallel to the electrode surface by histidine ligation in Hemin-His model, while the electron transport of hemin in Hemin-MHN model with ODT becomes relatively difficult.
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