Journal
ENVIRONMENTAL POLLUTION
Volume 333, Issue -, Pages -Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.envpol.2023.122057
Keywords
Organic pollutant; Photocatalyst; Tetracycline; Wastewater
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In this study, oxalic acid-induced chemically functionalized graphitic carbon nitride (OCN) was prepared using a one-pot calcination method. The OCN exhibited a highly porous structure with enhanced surface area and abundant amino groups, resulting in a maximum tetracycline removal of 92% within 90 min of visible light illumination. The increased presence of amino groups and enhanced visible light absorption were attributed to the exceptional photocatalytic efficacy of the functionalized OCN.
The facile preparation of visible-light-driven low-cost photocatalysts with extraordinary catalytic activity is highly beneficial in treating emerging pharmaceutical contaminants. Herein, oxalic acid-induced chemically functionalized graphitic carbon nitride (OCN) was prepared using a one-pot calcination method for the degra-dation of tetracycline. The estimated structural, morphological, and optical properties proved the formation of highly porous oxalic acid functionalized g-C3N4 (OCN) with enhanced surface area and abundant amino groups. The photocatalytic degradation studies reported a maximum tetracycline removal of 92% within 90 min of visible light illumination and followed pseudo-first-order kinetics (k = 0.03068min 1). The phenomenal pho-tocatalytic efficacy of the functionalized OCN is ascribed to the increased presence of amino groups, strength-ening visible light absorption. The enriched surface area also generated many active sites for the reclamation of tetracycline. The radicals trapping studies show that holes and superoxides are mainly responsible for the redemption of tetracycline. The degradation pathways of the tetracycline using OCN were predicted using HRMS. This study provides more insights into the reclamation of tetracycline using a highly efficient metal-free photocatalyst.
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