4.7 Article

Airborne hydrophilic microplastics in cloud water at high altitudes and their role in cloud formation

Journal

ENVIRONMENTAL CHEMISTRY LETTERS
Volume 21, Issue 6, Pages 3055-3062

Publisher

SPRINGER HEIDELBERG
DOI: 10.1007/s10311-023-01626-x

Keywords

Cloud water; Airborne microplastics; & mu;FTIR spectroscopy; Air pollution

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Microplastic pollution is widespread in most ecosystems, but little is known about their presence in high altitude clouds and their impact on cloud formation and climate change. In this study, microplastics in cloud water collected from the summits of Japanese mountains were analyzed. Nine types of microplastics were found, and they were fragmented with concentrations ranging from 6.7 to 13.9 pieces per liter. Microplastics with hydrophilic groups were abundant, suggesting their potential role as condensation nuclei for cloud ice and water. These findings indicate that high-altitude microplastics can influence cloud formation and potentially modify the climate.
Microplastic pollution is occurring in most ecosystem, yet their presence in high altitude clouds and their influence on cloud formation and climate change are poorly known. Here we analyzed microplastics in cloud water sampled at the summits of Japan mountains at 1300-3776 m altitude by attenuated total reflection imaging and micro-Fourier transform infrared spectroscopy. We observed nine microplastics including polyethylene, polypropylene, polyethylene terephthalate, polymethyl methacrylate, polyamide 6, polycarbonate, ethylene-propylene copolymer or polyethylene-polypropylene alloy, polyurethane, and epoxy resin. Microplastic were fragmented, with mean concentrations ranging from 6.7 to 13.9 pieces per liter, and with Feret diameters ranging from 7.1 to 94.6 mu m. Microplastics bearing hydrophilic groups such as carbonyl and/or hydroxyl groups were abundant, suggesting that they might have acted as condensation nuclei of cloud ice and water. Overall, our finding suggest that high-altitude microplastics cloud influence cloud formation and, in turn, might modify the climate.

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