Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 26, Pages 5766-5769Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc10361k
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Funding
- National Natural Science Foundation of China [21274165]
- Distinguished Professor Research Fund from Central South University of China
- National Science Foundation of U.S.A [CHE-1151991]
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The initial metallopolymer, derived from two different organic building blocks, is a kinetic intermediate to the final stable hexanuclear (bearing 4Ru(2+) and 2Fe(2+)) metallomacrocycle obtained through a thermodynamic dis-assembly/re-assembly route. The heteroleptic metallomacrocyclic architecture was characterized by NMR, UV, IR, CV, 2D-ROESY, DOSY, and ESI-MS.
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