4.7 Article

A zero CO(2 )emissions large ship fuelled by an ammonia-hydrogen blend: Reaching the decarbonisation goals

Journal

ENERGY CONVERSION AND MANAGEMENT
Volume 293, Issue -, Pages -

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.enconman.2023.117497

Keywords

Ammonia; Decarbonisation; Hydrogen; Internal combustion engine; Ship

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In order to achieve decarbonisation goals, a zero CO2 emissions large ship propulsion system is proposed, where a large ferry is powered by an internal combustion engine using an ammonia-hydrogen blend as fuel. Only ammonia is loaded onto the vessel, and the required hydrogen for engine combustion is produced onboard through ammonia decomposition. A selective catalytic reduction (SCR) reactor is designed to address NOx emissions. The system's energy and exergy efficiencies are evaluated to be 42.4% and 48.1% respectively, while the total capital cost is estimated to be 8.66 Meuro (784 euro/kW) with operating costs ranging from 210 euro/MWh to 243 euro/MWh. A sensitivity analysis demonstrates the feasibility of reducing operating costs to below 150 euro/MWh in the near future.
To reach the decarbonisation goals, a zero CO2 emissions large ship propulsion system is proposed in this work. The ship selected is a large ferry propelled by an internal combustion engine fuelled by an ammonia-hydrogen blend. The only fuel loaded in the vessel will be ammonia. The hydrogen required for the combustion in the engine will be produced onboard employing ammonia decomposition. The heat required for this decomposition section will be supplied by using the hot flue gases of the combustion engine. To address the issues regarding NOx emissions, a selective catalytic reduction (SCR) reactor was designed. The main operating variables for all the equipment were computed for engine load values of 25%, 50%, 75%, and 100%. Considering the lowest SCR removal rate (91% at an engine load of 100%), the NOx emissions of the vessel were less than 0.5 g/kWh, lower than the IMO requirements. An energy analysis of the system proposed to transform ammonia into energy for shipping was conducted. The global energy and exergy efficiencies were 42.4% and 48.1%. In addition, an economic analysis of the system was performed. The total capital cost (CAPEX) for the system can be estimated at 8.66 Meuro (784 euro/kW) while the operating cost (OPEX) ranges between 210 euro/MWh (engine load 100%) and 243 euro/MWh (engine load of 25%). Finally, a sensitivity analysis for the price of ammonia was performed resulting in the feasibility of reducing the operating cost to below 150 euro/MWh in the near horizon.

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