4.7 Article

Mineral-impregnated carbon-fiber based reinforcing grids as thermal energy harvesters: A proof-of-concept study towards multifunctional building materials

Journal

ENERGY AND BUILDINGS
Volume 298, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.enbuild.2023.113564

Keywords

Carbon-fiber composite; Mineral impregnation; Geopolymer; Smart textile reinforcement; Large-scale thermal energy harvesting

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This proof-of-concept study demonstrates the fabrication of a multifunctional reinforcing grid-building material within a thermoelectric element generator configuration. Carbon fiber yarns were impregnated with a geopolymer-based suspension and tested for their properties. The resulting hardened mineral-impregnated carbon-fiber reinforcements were used as thermoelements to assemble a grid-like TEG, which generated power upon exposure to a temperature difference.
This proof-of-concept study demonstrates for the first time the fabrication of a multifunctional reinforcing grid-building material within a thermoelectric element generator (TEG) configuration. Commercially available carbon fiber yarns, which possess inherent Seebeck coefficient (S) values of-2.5 mu V/K (n-type) and +7.4 mu V/K (p-type), were thoroughly investigated prior to their impregnation with a geopolymer (GP)-based suspension. The resulting hardened mineral-impregnated carbon-fiber (MCF) reinforcements were subsequently tested regarding their physicochemical and mechanical properties. Afterward, individual MCFs were employed as n-/p-type thermoelements to assemble a grid-like TEG consisting of five serially interconnected junctions. The TEG-enabled reinforcing grid exhibited a voltage output of 1.8 mV, corresponding to a generated power of 22.3 nW upon exposure to an in-plane temperature difference (Delta T) of 50 K. Multifunctional building materials are envisaged to exploit thermal gradients on a large-scale during their service lifetime, contributing towards zero energy consumption constructions.

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