Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 17, Pages 3663-3666Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc09055a
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- King Abdullah University of Science and Technology
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By associating primary (slow but controlled ring-opening polymerization; ROP) and tertiary (fast but uncontrolled ROP) amines in the same molecule, a novel highly active organocatalytic system proceeding by an accelerated amine mechanism through monomer activation (AAMMA) and leading to living ROP of alpha-amino acid N-carboxy-anhydrides at room temperature was successfully developed.
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