4.7 Article

On Zn(II) 2,2′-bisdipyrrin circular helicates

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 27, Pages 5906-5909

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc00724k

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Funding

  1. Universite de Strasbourg
  2. Institut Universitaire de France
  3. International centre for Frontier Research in Chemistry (icFRC)
  4. C.N.R.S
  5. Ministere de l'Enseignement Superieur et de la Recherche

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Coordination of two 2,2'-bisdipyrrin ligands, bearing methyl ester or methylthioether peripheral groups, with Zn(II) cations leads not only to the formation of the expected linear helicates but also concomitantly to novel tri- and tetra-nuclear circular species that have been isolated and fully characterized in solution and by X-ray diffraction.

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