Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 94, Pages 16767-16770Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc07306e
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Funding
- National Natural Science Foundation of China [21402201, 21471150, 21221001]
- start-up foundation from FJIRSM-CAS
- award of The Recruitment Program of Global Youth Experts
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A M2L4 cage with D-4 symmetry was self-assembled from four anthracene-bridged benzimidazole ligands and two Pd-II ions. The cage features a concise hydrophobic pocket wrapped up by the anthracene walls with eight hydrogen-bond donors pointing inward, which provide a specific binding site for nitrate, with a binding affinity at least two orders of magnitude higher than all the other anions screened including halide anions, which have a very similar ionic radius and charge density.
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